Synthesis and Utility of Dihydropyridine Boronic Esters
نویسندگان
چکیده
منابع مشابه
Stereodivergent Olefination of Enantioenriched Boronic Esters
A stereodivergent coupling reaction between vinyl halides and boronic esters is described. This coupling process proceeds without a transition-metal catalyst, instead proceeding by electrophilic selenation or iodination of a vinyl boronate complex followed by stereospecific syn or anti elimination. Chiral, nonracemic boronic esters could be coupled with complete enantiospecificity. The process ...
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15 صفحه اولStereospecific functionalizations and transformations of secondary and tertiary boronic esters.
The formation of highly enantioenriched boronic esters through both stoichiometric and catalytic methods has received much attention over the past decade. Accordingly, the transformations of the boronic ester moiety into other functional groups is of considerable interest in synthesis. Specifically, transformations which retain the high enantioenrichment of the starting boronic ester, either th...
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ژورنال
عنوان ژورنال: Angewandte Chemie International Edition
سال: 2015
ISSN: 1433-7851,1521-3773
DOI: 10.1002/anie.201510027